Magnetic MOF microreactors for recyclable size-selective biocatalysis† †Electronic supplementary information (ESI) available: Experimental procedures, calibration curves and additional figures relating to capsule characterisation and biocatalysis. See DOI: 10.1039/c4sc03367a Click here for additional data file.

Magnetic MOF microreactors for recyclable size-selective biocatalysis.

In this contribution we report a synthetic strategy for the encapsulation of functional biomolecules within MOF-based microcapsules. We employ an agarose hydrogel droplet Pickering-stabilised by UiO-66 and magnetite nanoparticles as a template around which to deposit a hierarchically structured ZIF-8 shell. The resulting microcapsules are robust, highly microporous and readily attracted to a ma...

A complex stereochemical relay approach to the antimalarial alkaloid ocimicide A1. Evidence for a structural revision† †Electronic supplementary information (ESI) available: Supplementary schemes, figures, and tables, general experimental remarks, synthetic procedures, catalogues of experimental and calculated nuclear magnetic resonance spectra. CCDC 1536046. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc01127j Click here for additional data file. Click here for additional data file.

Selective glycoprotein detection through covalent templating and allosteric click-imprinting† †Electronic supplementary information (ESI) available: Synthetic procedures, synthesis of DFC, NMR spectra, surface modification and characterisation in addition to SPR analysis. See DOI: 10.1039/c5sc02031j Click here for additional data file.

Enantioselective Narasaka–Heck cyclizations: synthesis of tetrasubstituted nitrogen-bearing stereocenters† †Electronic supplementary information (ESI) available: Experimental procedures and characterisation data for all compounds are provided. CCDC 1438659 and 1438660. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc04466b Click here for additional data file. Click here for additional data file.

School of Chemistry, University of Bristol, B bris.ac.uk AstraZeneca, Alderley Park, Maccleseld, C AstraZeneca, Pepparedsleden 1, Mölndal, 4 † Electronic supplementary information ( and characterisation data for all compou 1438660. For ESI and crystallographic dat DOI: 10.1039/c6sc04466b ‡ These authors contributed equally. § Author to whom correspondence shou structures of 3b and Pd[(Sa,S)-L-...

Light driven mesoscale assembly of a coordination polymeric gelator into flowers and stars with distinct properties† †Electronic supplementary information (ESI) available: Text, figures, and tables depicting different synthetic procedures, detailed experimental procedures, characterisation data including FT-IR, microscopic analyses, TGA, EDAX and SAED analyses, pore size distribution. See DOI: 10.1039/c5sc02233a Click here for additional data file.